Name | Sodium formaldehydesulfoxylate dihydrate |
Synonyms | Rongalite Sodium hydroxymethanesulfinate Sodium formaldehyde-sulfoxylate Formaldehyde sodium sulfoxylate Sodium formaldehyde sulphoxylate sodium hydroxymethanesulfinate dihydrate Sodium formaldehydesulfoxylate dihydrate Hydroxymethanesulfinic acid monosodium salt dihydrate |
CAS | 6035-47-8 |
EINECS | 611-965-8 |
InChI | InChI=1/CH4O3S.Na.2H2O/c2-1-5(3)4;;;/h2H,1H2,(H,3,4);;2*1H2/q;+1;;/p-1 |
Molecular Formula | CH3NaO3S·2H2O |
Molar Mass | 154.12 |
Density | 1.8 g/cm3 (20℃) |
Melting Point | 63-64℃ |
Boling Point | 446.4°C at 760 mmHg |
Flash Point | 223.8°C |
Vapor Presure | 7.6E-10mmHg at 25°C |
Appearance | White crystal |
Storage Condition | Room Temprature |
MDL | MFCD00150598 |
Physical and Chemical Properties | The chemical product is white crystal. Soluble in water. Insoluble in anhydrous ethanol, ether, benzene. It has strong reducibility at high temperature. It has fading performance. Decompose at high temperature to produce formaldehyde, hydrogen sulfide and other toxic gases. When it encounters dilute acid, it decomposes, and its solution is neutral. Anhydrous melting point 63~64 ℃. The surface density is 1.80~1.85g/cm3. |
Use | This product is used in the printing and dyeing industry as a white pulling agent, reducing agent, bleaching agent and the production of indigo dye, vat dye. It can also be used in the polymerization of synthetic rubber, sugar and ethylene compounds. |
Hazard Symbols | Xn - Harmful |
Risk Codes | R31 - Contact with acids liberates toxic gas R68 - Possible risk of irreversible effects |
Safety Description | S24/25 - Avoid contact with skin and eyes. |
Raw Materials | ZINC HYDROSULFITE |
Downstream Products | microdispersoid acrylate resin filling emulsion Neoarsphenamine |
Rat oral LD50>2000mg/kg; The oral LD50 of mice is 4000mg/kg. The finished bucket of carved white blocks should be stored in a dry and cool place to prevent exposure to sunlight and rain. It should not be mixed with oxidants and acids, and the storage room should not contain acidic vapors.
1. Add 286kg of zinc powder and 500kg of water to the pulping tank, form a slurry, and then add it to a tubular reactor. Circularly absorb about 550kg of SO2 to prepare zinc bisulfite (reaction temperature maintained at 40-45 ℃, endpoint pH value of 3-3.5).
2. Add 698kg of 40% formaldehyde to the reaction kettle, stir and add the aforementioned zinc bisulfite aqueous solution dropwise, and gradually raise the temperature. When the temperature rises to 95-100 ℃, add a total of 257kg of zinc powder in batches, and react under insulation for several hours. The end point is when the content of the unreacted substance is less than 1%. Allow the sediment to settle and transfer it to the displacement kettle. Wash with clean water and add 755kg of 42% sodium hydroxide solution under stirring. React at 65 ℃ until the free alkali content reaches 0.3%~0.5%. Press and filter the reactants to remove impurities, clarify the filtrate for 48 hours, and then perform vacuum concentration. After cooling and crystallization, the finished product is obtained by crushing.